GAS-PHASE ELECTRON RESONANCE SPECTRA OF SF AND SEF

被引：75
|
作者：
CARRINGTON, A
CURRIE, GN
MILLER, TA
机构：
[1] Department of Chemistry, University of Southampton, Southampton
[2] Department of Chemistry, James Franck Institute, University of Chicago, Chicago, IL
[3] Bell Telephone Laboratories, Murray Hill, NJ
来源：
JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 06期
关键词：
D O I：
10.1063/1.1671436
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electron resonance spectra of the gaseous radicals SF and SeF have been detected and analyzed. The derivation of an effective Hamiltonian which operates in the rotational subspace of the ground vibronic state is described. Use of this Hamiltonian yields the rotational constants, the fine-structure splittings, and the axial components of the 19F hyperfine interaction for both radicals.
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页码：2726 / +
页数：1
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