DITERPENE MALONATES AND OTHER TERPENES FROM NARDIA-SUCCULENTA AND N-SCALARIS

被引:17
作者
LANGENBAHN, U [1 ]
BURKHARDT, G [1 ]
BECKER, H [1 ]
机构
[1] UNIV SAARLAND,FR 123,W-6600 SAARBRUCKEN,GERMANY
关键词
NARDIA-SUCCULENTA; N-SCALARIS; JUNGERMANNIALES; LIVERWORTS; KAURANES; LABDANES; MALONATES;
D O I
10.1016/0031-9422(93)85044-R
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Nardia succulenta and N. scalaris afforded a series of 12 diterpene malonates: ent-kaur-16-en-15beta-yl hydrogen malonate; ent-labda-8(17), 13-dien-15-yl hydrogen malonate; bis-ent-kaur-16-en-15beta-yl malonate; bis-ent-labda-8(17), 13-dien-15-yl malonate; ent-kaur-16-en-15beta-yl ent-labda-8(17), 13-dien-15-yl malonate; ent-kaur-16-en-15beta-yl phytyl malonate; (14-ent-kaur-16-en-14-yl hydrogen malonate; bis-(14-ent-kaur-16-en-14-yl malonate; (14R)-ent-kaur-16-en-14-yl phytyl malonate; (14R)-ent-kaur-16-en-14-yl epi-bornyl malonate; ent-kaur-16-en-15beta-yl epibornyl malonate and (14R)-ent-kaur-16-en-14-yl fenchyl malonate; besides (1,2)-bis-nor-phytone and two diastereomeric 3,6-peroxo-cupar-1-enes.
引用
收藏
页码:1173 / 1179
页数:7
相关论文
共 17 条
[1]   NEW TRANS-FUSED AFRICANOLS FROM LEPTOGRAPHIUM-LUNDBERGII [J].
ABRAHAM, WR ;
ERNST, L ;
WITTE, L ;
HANSSEN, HP ;
SPRECHER, E .
TETRAHEDRON, 1986, 42 (16) :4475-4480
[2]   GARRYFOLINE-CUAUCHICHICINE REARRANGEMENT - A STUDY OF MECHANISM IN (-)-KAURENOLS [J].
BARNES, MF ;
MACMILLAN, J .
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (05) :361-+
[3]   C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY OF NATURALLY-OCCURRING SUBSTANCES .81. CMR SPECTROSCOPY OF LABDANIC DITERPENES AND RELATED SUBSTANCES [J].
BASTARD, J ;
DUC, DK ;
FETIZON, M ;
FRANCIS, MJ ;
GRANT, PK ;
WEAVERS, RT ;
KANEKO, C ;
BADDELEY, GV ;
BERNASSAU, JM ;
BURFITT, IR ;
WOVKULICH, PM ;
WENKERT, E .
JOURNAL OF NATURAL PRODUCTS, 1984, 47 (04) :592-599
[4]   NATURALLY OCCURRING TERPENE DERIVATIVES .180. NEW LABDANE DERIVATIVES AND OTHER SUBSTANCES FROM RELHANIA-ACEROSA [J].
BOHLMANN, F ;
JAKUPOVIC, J .
PHYTOCHEMISTRY, 1979, 18 (04) :631-635
[5]   C-13 NMR-SPECTRA OF MONOTERPENES [J].
BOHLMANN, F ;
ZEISBERG, R ;
KLEIN, E .
ORGANIC MAGNETIC RESONANCE, 1975, 7 (09) :426-432
[6]  
CONNOLLY JD, 1984, J CHEM RES-S, P94
[7]  
FRAHM JP, 1983, MOOSFLORA, P110
[8]  
Hernandez J., 1992, Fitoterapia, V63, P377
[9]  
Herz W., 1984, PROGR CHEM NATURAL P, V46, P77
[10]   TERPENOIDS .3. ENOLIZATION-KETONIZATION AND OPTICAL ROTATORY DISPERSION OF ENT-KAURAN-15-ONES AND 13-BETA-KAURAN-15-ONES [J].
MACMILLAN, J ;
WALKER, ERH .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1972, (07) :986-+