MACRO-AZO-INITIATORS COMPOSED OF VARIOUS POLYESTERS - THEIR SYNTHESES, THERMAL-PROPERTIES, AND APPLICATION TO BLOCK COPOLYMERIZATION

被引：28
作者：
HANEDA, Y
TERADA, H
YOSHIDA, M
UEDA, A
NAGAI, S
机构：
[1] KYUSHU UNIV,FAC ENGN,DEPT CHEM SCI & TECHNOL,6-10-1 HAKOZAKI,HIGASHI KU,FUKUOKA 812,JAPAN
[2] OSAKA MUNICIPAL TECH RES INST,JOTO KU,OSAKA 536,JAPAN
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1994年 / 32卷 / 14期
关键词：
MACRO-AZO-INITIATORS; RADICAL POLYMERIZATION; BLOCK COPOLYMERIZATION; POLYESTER-B-POLYSTYRENE; POLYESTER-B-POLY(METHYLMETHACRYLATE); POLYCAPROLACTONE-B-POLYSTYRENE; POLY(ALIPHATIC CARBONATE)-B-POLYSTYRENE;
D O I：
10.1002/pola.1994.080321405
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Various aliphatic polyesters such as poly (ethyleneadipate), poly (tetramethylene adipate), poly (caprolactone), and poly (carbonate) were condensed with 4,4'-azobis-4-cyanopentanoyl chloride to prepare macro-azo-initiators. Their thermal properties, observed by differential scanning calorimetry, showed similar decomposition behavior to each other. Block copolymers containing each of these polyesters as a block segment combined polystyrene or poly (methylmethacrylate) have been derived by the polymerization of monomers initiated with these macro-azo-initiators. (C) 1994 John Wiley & Sons, Inc.
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页码：2641 / 2652
页数：12
相关论文
共 21 条
[1]  
AHN TO, 1990, POLYM PREPR JPN, V39, P25
[2]   PROPERTIES OF (BA)N-B TYPE BLOCK COPOLYMERS OF BUTADIENE AND DIMETHYL ITACONATE PREPARED USING MACROAZONITRILE INITIATORS [J].
COWIE, JMG ;
YAZDANIPEDRAM, M .
BRITISH POLYMER JOURNAL, 1984, 16 (03) :127-133
[3]  
HAZER B, 1989, MAKROMOL CHEM, V190, P1987
[4]   SURFACE CHARACTERISTICS OF POLYDIMETHYLSILOXANE-POLY(METHYL METHACRYLATE) BLOCK COPOLYMERS AND THEIR PMMA BLENDS [J].
INOUE, H ;
MATSUMOTO, A ;
MATSUKAWA, K ;
UEDA, A ;
NAGAI, S .
JOURNAL OF APPLIED POLYMER SCIENCE, 1990, 41 (7-8) :1815-1829
[5]   BLOCK COPOLYMERS DERIVED FROM AZOBISCYANOPENTANOIC ACID .11. PROPERTIES OF SILICONE PMMA BLOCK COPOLYMERS PREPARED VIA POLYSILOXANE(AZOBISCYANOPENTANAMIDE)S [J].
INOUE, H ;
UEDA, A ;
NAGAI, S .
JOURNAL OF APPLIED POLYMER SCIENCE, 1988, 35 (08) :2039-2051
[6]   SURFACE CHARACTERISTICS OF FLUOROALKYLSILICONE - POLY(METHYL METHACRYLATE) BLOCK COPOLYMERS AND THEIR PMMA BLENDS [J].
INOUE, H ;
MATSUMOTO, A ;
MATSUKAWA, K ;
UEDA, A ;
NAGAI, S .
JOURNAL OF APPLIED POLYMER SCIENCE, 1990, 40 (11-12) :1917-1938
[7]  
KITA Y, 1986, CHEM EXPRESS, V1, P543
[8]  
KURUK H, 1986, J APPL POLYM SCI, V31, P2171
[9]   DIRECT POLYCONDENSATION OF 4,4'-AZOBIS-4-CYANOPENTANOIC ACID WITH DIOLS AND DIAMINES USING 1-METHYL-2-CHLOROPYRIDINIUM IODIDE [J].
MATSUKAWA, K ;
UEDA, A ;
INOUE, H .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1990, 28 (08) :2107-2114
[10]  
MATSUKAWA K, 1987, CHEM EXPRESS, V2, P33
123