PROPERTIES OF THE BETA-CARBONYLALKYLTIN CHLORIDES - EVIDENCE FOR INTRA-MOLECULAR COORDINATION

被引：22

作者：

HAIGH, RM

DAVIES, AG

TSE, MW

机构：

[1] Chemistry Department, University College London, London, WC1H OAJ

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)91500-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Mössbauer spectra and the solvent effect on the 1H NMR spectra support the conclusions from infrared spectroscopy that the compounds Cl3 SnCR2 CRHCOX and the Cl2 Sn(CR2 CRHCOX)2 (R = Me or H; X = Me, OH, or OAlkyl) are intramolecularly coordinated in both the solid state and in solution. The compounds Cl3 SnCR2 CRHCOX (X = OH or OAlkyl) react with t-butoxyl radicals in solution to show the ESR spectra of the displaced radicals CR2 CRHCOX. © 1979.

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页码：163 / 167

页数：5

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