KINETICS OF REACTIONS OF NP AND PU WITH HYDRAZINE DERIVATIVES .13. CATALYSIS BY TC(VII) OF THE REACTION BETWEEN PU(IV) AND 2-HYDROXYETHYLHYDRAZINE

被引：0

作者：

KOLTUNOV, VS

ZHURAVLEVA, GI

SHAPOVALOV, MP

机构：

来源：

RADIOCHEMISTRY | 1993年 / 35卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The mechanism of the catalysis by Tc(VII) of the reaction between Pu (IV) and 2-hydroxyethylhydrazine includes slow steps for the reduction of Tc(VII) to Tc(IV) by 2-hydroxyethylhydrazine and oxidation of Tc(IV) by Pu(IV). Numerical processing of the experimental data using a computer yielded the kinetic equations and the rate constants and activation energies of these reaction steps.

引用

页码：650 / 655

页数：6

共 24 条

[1] KINETICS OF REACTIONS OF NP AND PU IONS WITH HYDRAZINE DERIVATIVES .9. CATALYSIS BY FE(III) OF THE REACTION BETWEEN PU(IV) AND 2-HYDROXYETHYLHYDRAZINE
KOLTUNOV, VS
ZHURAVLEVA, GI
BARANOV, SM
SOVIET RADIOCHEMISTRY, 1991, 33 (05): : 531 - 536
[2] KINETICS OF REACTION OF NP AND PU WITH HYDRAZINE DERIVATIVES .7. 2-HYDROXYETHYLHYDRAZINE
BARANOV, SM
KOLTUNOV, VS
SOVIET RADIOCHEMISTRY, 1991, 33 (04): : 353 - 358
[3] Kinetics of reactions of Np and Pu ions with hydrazine derivatives: XVII. Reaction of Pu(VI) with hydroxyethylhydrazine
Koltunov V.S.
Pastushchak V.G.
Mezhov E.A.
Koltunov G.V.
Radiochemistry, 2004, 46 (2) : 125 - 130
[4] Kinetics of reactions of Np and Pu ions with hydrazine derivatives: XVIII. Reaction between Np(V) and hydroxyethylhydrazine
Koltunov V.S.
Baranov S.M.
Koltunov G.V.
Radiochemistry, 2005, 47 (2) : 168 - 172
[5] KINETICS OF REACTIONS OF NP AND PU IONS WITH HYDRAZINE DERIVATIVES .3. REDUCTION OF PU(IV) BY METHYL HYDRAZINE AND CATALYSIS OF REACTION BY MO(VI) IONS
KOLTUNOV, VS
BARANOV, SM
ZHURAVLEVA, GI
SOVIET RADIOCHEMISTRY, 1989, 31 (01): : 47 - 52
[6] KINETICS OF TECHNETIUM REACTIONS .13. REDUCTION OF TC(VII) WITH HYDROXYETHYLHYDRAZINE
GOMONOVA, TV
KOLTUNOV, VS
RADIOCHEMISTRY, 1995, 37 (05) : 381 - 383
[7] KINETICS AND MECHANISM OF NP AND PU REACTIONS WITH ORGANIC DERIVATIVES OF HYDRAZINE
KOLTUNOV, VS
BARANOV, SM
INORGANICA CHIMICA ACTA, 1987, 140 (1-2) : 31 - 34
[8] KINETICS OF REACTIONS OF NP AND PU IONS WITH HYDRAZINE DERIVATIVES .1. REACTION BETWEEN NP(VI) AND METHYLHYDRAZINE
KOLTUNOV, VS
BARANOV, SM
ZHAROVA, TP
SOVIET RADIOCHEMISTRY, 1987, 29 (02): : 142 - 146
[9] KINETICS OF THE REACTION OF NP AND PU WITH HYDRAZINE DERIVATIVES .12. REACTION BETWEEN NP(VI) AND PHENYLHYDRAZINE
KOLTUNOV, VS
BARANOV, SM
ZHAROVA, TP
RADIOCHEMISTRY, 1993, 35 (03) : 275 - 280
[10] KINETICS OF REACTIONS OF NP AND PU IONS WITH HYDRAZINE DERIVATIVES .2. REACTIONS OF NP(VI) WITH ETHYL DERIVATIVES
KOLTUNOV, VS
BARANOV, SM
TIKHONOV, MF
SOVIET RADIOCHEMISTRY, 1989, 31 (01): : 41 - 46

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