MOLYBDENIUM MEDIATED PREPARATION OF CYCLOPENTENONES

被引：79

作者：

JEONG, N ^{[1
]}

LEE, SJ ^{[1
]}

LEE, BY ^{[1
]}

CHUNG, YK ^{[1
]}

机构：

[1] SEOUL NATL UNIV,DEPT CHEM,SEOUL 151,SOUTH KOREA

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 25期

关键词：

D O I：

10.1016/S0040-4039(00)60607-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cocyclization of alkynes, alkenes and carbon monoxide was achieved in the presence of a stoichiometric amount of molybdenium hexacarbonyl and excess of dimethylsulfoxide. This process will constitute another version of Pauson-Khand reaction.

引用

页码：4027 / 4030

页数：4

共 23 条

[1] THE SYNTHESIS OF NITROGEN-HETEROCYCLES VIA THE INTRAMOLECULAR KHAND REACTION - FORMATION OF TETRA-HYDROCYCLOPENTA[C]PYRROL-5(1H)-ONES AND HEXA-HYDROCYCLOPENTA[C]PYRROL-5(1H)-ONES AND HEXAHYDRO-6H-2-PYRINDIN-6-ONES [J].

BROWN, SW ;

PAUSON, PL .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1990, (04) :1205-1209

[2] PROMOTERS FOR THE (ALKYNE)HEXACARBONYLDICOBALT-BASED CYCLOPENTENONE SYNTHESIS [J].

CHUNG, YK ;

LEE, BY ;

JEONG, N ;

HUDECEK, M ;

PAUSON, PL .

ORGANOMETALLICS, 1993, 12 (01) :220-223

[3] GENERAL-SYNTHESIS OF OMEGA-ACETYLENIC VINYL ESTERS AND ETHERS [J].

CROUDACE, MC ;

SCHORE, NE .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (26) :5357-5363

[4] REDUCTIVE CYCLIZATION OF ESTER-CONTAINING ENYNES WITH A PRACTICAL TITANOCENE REAGENT - SYNTHESIS OF BICYCLIC CYCLOPENTENONES AND IMINOCYCLOPENTENES [J].

GROSSMAN, RB ;

BUCHWALD, SL .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (22) :5803-5805

[5] REACTIONS OF PENTACARBONYL(1-METHOXYETHYLIDENE)MOLYBDENUM AND PENTACARBONYL(1-METHOXYETHYLIDENE)TUNGSTEN WITH ALPHA,OMEGA-ENYNES - COMPARISON WITH THE CHROMIUM ANALOG AND RESULTING MECHANISTIC RAMIFICATIONS [J].

HOYE, TR ;

SURIANO, JA .

ORGANOMETALLICS, 1992, 11 (06) :2044-2050

[6] AN EFFICIENT PREPARATION OF 3-AZABICYCLO[3.3.0]OCT-5-EN-7-ONES FROM PROPARGYL ALCOHOL-COBALT COMPLEXES VIA NICHOLAS REACTION WITH AMIDIC NITROGEN NUCLEOPHILES FOLLOWED BY PAUSON-KHAND CYCLIZATION [J].

JEONG, N ;

YOO, SE ;

LEE, SJ ;

LEE, SH ;

CHUNG, YK .

TETRAHEDRON LETTERS, 1991, 32 (19) :2137-2140

[7]

JEONG N, 1991, SYNLETT, P204

[8] SYNTHESIS OF THE ANGULARLY FUSED TRIQUINANE SKELETON VIA INTRAMOLECULAR ORGANOMETALLIC CYCLIZATION [J].

KNUDSEN, MJ ;

SCHORE, NE .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (25) :5025-5026

[9] DICOBALTOCTACARBONYL ALKYNE COMPLEXES AS INTERMEDIATES IN THE SYNTHESIS OF BICYCLO[3.3.0]OCTENONES FOR THE SYNTHESIS OF CORIOLIN AND HIRSUTIC ACID [J].

MAGNUS, P ;

EXON, C ;

ALBAUGHROBERTSON, P .

TETRAHEDRON, 1985, 41 (24) :5861-5869

[10]

MAGNUS P, 1987, J ORG CHEM, V52, P148

← 1 2 3 →