ENANTIOCONTROL BY INTRINSIC ANTIPARALLEL DOUBLE REPULSION ON DIACETONE-D-GLUCOSE TEMPLATE - ENANTIOSELECTIVE SYNTHESIS OF ALANINE AND CHIRALLY DEUTERATED GLYCINE

被引：16

作者：

KAKINUMA, K

KOUDATE, T

LI, HY

EGUCHI, T

机构：

[1] Department of Chemistry, Tokyo Institute of Technology O-okayama, Meguro-ku, Tokyo

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(00)93559-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A divergent and highly enantioselective synthetic methodology not only for both enantiomers of alpha-amino acids but for both chirally deuterated glycines from a single starting material was developed by making use of stereocontrol with antiparallel double repulsion on the diacetone-D-glucos-3-ulose template.

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页码：5801 / 5804

页数：4

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