Perhaloarylmetal Chemistry. V. The Formation and Properties of Some sigma-Perhaloaryl and Methyl Derivatives of Nickel(1,2)

被引：48

作者：

Rausch, M. D. ^{[1
]}

Tibbetts, F. E. ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01002 USA

来源：

INORGANIC CHEMISTRY | 1970年 / 9卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ic50085a016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new series of air-stable, a-bonded organic derivatives of nickel of the types [CH3(Col-le)2P](2)Ni(aryl)C1, (CH2(CeHe)(2)P2-Ni(ary1)2, and [CH3(CH3)(2)P](2)Ni(aryl)CH3 is described. Their proton nmr spectra are consistent with a trans-planar configuration in each case. Factors affecting the relative stabilites of these products are discussed.

引用

页码：512 / 516

页数：5

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