LONG-RANGE COUPLING IN A MIXED-VALENCE DIRUTHENIUM COMPLEXES CONTAINING BIS-TERPYRIDINE LIGANDS OF VARIOUS LENGTHS AS BRIDGES

被引：144

作者：

COLLIN, JP ^{[1
]}

LAINE, P ^{[1
]}

LAUNAY, JP ^{[1
]}

SAUVAGE, JP ^{[1
]}

SOUR, A ^{[1
]}

机构：

[1] CNRS,CTR ELABORAT MAT & ETUD STRUCT,F-31055 TOULOUSE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 05期

关键词：

D O I：

10.1039/c39930000434

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dinuclear ruthenium(II) complexes have been prepared which contain back-to-back bis-terpyridine ligands of various lengths (Ru ... Ru distances between 7 and 20 angstrom) as bridges; significant electronic coupling is observed in mixed-valence states, even for the system with the longest separation.

引用

页码：434 / 435

页数：2

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