SYNTHESIS AND CHARACTERIZATION OF THE BIS-ARENE SANDWICH CLUSTER [RU6C(CO)11(ETA-6-C6H3ME3-1,3,5)2]

被引：20

作者：

BRAGA, D

GREPIONI, F

RIGHI, S

JOHNSON, BFG

BAILEY, PJ

DYSON, PJ

LEWIS, J

MARTINELLI, M

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

[2] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 13期

关键词：

D O I：

10.1039/dt9920002121

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bis-arene cluster complex [Ru6C(CO)11(eta-6-C6H3Me3-1,3,5)2] 1 has been synthesised and characterized by single-crystal X-ray diffraction; it possesses a unique structure in which the octahedral cluster core is sandwiched between the two arenes.

引用

页码：2121 / 2122

页数：2

共 5 条

[1] THE SYNTHESIS, MOLECULAR-STRUCTURE AND INTERCONVERSION OF 2 NOVEL BENZENE-COORDINATED PENTARUTHENIUM CARBIDO CLUSTER ISOMERS [RU5C(CO)12(MU-3-ETA-2-ETA-2-ETA-2-C6H6)] AND [RU5C(CO)12(ETA-6-C6H6)] [J].

BAILEY, PJ ;

BRAGA, D ;

DYSON, PJ ;

GREPIONI, F ;

JOHNSON, BFG ;

LEWIS, J ;

SABATINO, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (02) :177-178

[2] MOLECULAR-ORGANIZATION AND DYNAMIC BEHAVIOR OF ARENE CLUSTER COMPLEXES IN THE SOLID-STATE - CRYSTAL-STRUCTURES OF [OS4H2(CO)10(ETA-6-C6H5ME)], [OS4H2(CO)10(ETA-6-C6H4ME2)] AND [RU6C(CO)14(ETA-6-C6H3ME3-1,3,5)] [J].

BRAGA, D ;

GREPIONI, F ;

JOHNSON, BFG ;

CHEN, H ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (10) :2559-2568

[3] STRUCTURE OF MU-6-CARBIDO-2,3-MU-CARBONYL-1,1,1,2,2,3,3,4,4,4,5,5,5-TRIDECACARBONYL-6-(ETA-6-TOLUENE)-OCTAHEDRO-HEXARUTHENIUM(12 RU-RU) [J].

FARRUGIA, LJ .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :997-998

[4] BENZENE IN A NEW FACE-CAPPING BONDING MODE - MOLECULAR-STRUCTURES OF [RU6C(CO)11(MU-3-ETA-2-ETA-2-ETA-2-C6H6)(ETA-6-C6H6)] AND [OS3(CO)9(MU-3-ETA-2-ETA-2-ETA-2-C6H6)] [J].

GOMEZSAL, MP ;

JOHNSON, BFG ;

LEWIS, J ;

RAITHBY, PR ;

WRIGHT, AH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (23) :1682-1684

[5]

MASON R, 1968, J CHEM SOC CHEM COMM, P468

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