AUTOXIDATIONS OF EARLY TRANSITION METALLOCENES .2. BIS(ETA-5-CYCLOPENTADIENYL)MOLYBDENUM(IV) DIALKYLS

被引：6

作者：

ATKINSON, JM ^{[1
]}

BRINDLEY, PB ^{[1
]}

机构：

[1] KINGSTON POLYTECH,PENRHYN RD,KINGSTON THAMES KT1 2EE,SURREY,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 411卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)86013-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Each of the compounds Cp2MoR2 (Cp = eta-5-cyclopendadienyl, R = neopentyl or benzyl) in aromatic hydrocarbon solvent containing dissolved oxygen forms a weak complex at temperatures close to ambient (DELTA-H THETA for Cp2Mo(neopentyl)2.O2 = -9.1 kJ mol-1). At higher temperatures (60-degrees-C) free radical autoxidation occurs (t1/2 = 1.25 h) to give a complex mixture of products.

引用

页码：139 / 145

页数：7

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