2 POLYMERIC MICELLAR FIBERS WITH GLUCONAMIDE HEAD GROUPS

被引：2
|
作者：
FUHRHOP, JH
SPIROSKI, D
SCHNIEDER, P
机构：
[1] Institut für Organische Chemie der Freie Universität Berlin, 1000 Berlin 33
来源：
REACTIVE POLYMERS | 1991年 / 15卷
关键词：
N-ALKYL-GLUCONAMIDE-6-METHACRYLATE; POLYLYSIN-GLUCONAMIDE; CHIRAL POLYMER FIBERS; ELECTRON MICROSCOPY;
D O I：
10.1016/0923-1137(91)90166-L
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Poly-L-lysine was converted to a comb-shaped amphiphile with dodecylgluconamide side chains. These micellar molecules could be directly observed by electron microscopy. They formed fibrous aggregates. N-octylgluconamide is known to aggregate to form double-helical fibers with very high length: width ratios (approximately 10(4):1). It was converted to a monomethacrylate in the head group-which polymerized upon UV-irradiation in DMSO / water emissions, but not in DMSO alone. Micellar polymers are of interest in the construction of complex reaction systems.
引用
收藏
页码：215 / 220
页数：6
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