CARBONYL HALIDES OF GROUP 6 TRANSITION METALS .6. COMPLEXES WITH BIS(DIPHENYLPHOSPHINO)METHANE

被引：44

作者：

ANKER, MW

COLTON, R

TOMKINS, IB

机构：

[1] Department of Inorganic Chemistry, University of Melbourne, Parkville, VIC

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1968年 / 21卷 / 05期

关键词：

D O I：

10.1071/CH9681143

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexes of the type MX2(CO)2 diphos2 [M = Mo, W; X = Cl, Br; diphos = bis(diphenylphosphino)methane] have been prepared and characterized. The complexes are neutral, diamagnetic, seven-coordinate species with one of the diphosphine molecules acting as a monodentate ligand. Nuclear magnetic resonance, conductance, and molecular weight studies support this view. The monomeric complex MoBr2(CO)3 diphos has also been prepared. © 1968 CSIRO. All rights reserved.

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页码：1143 / &

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