THERMOCHEMICAL AND ELECTROCHEMICAL STUDY OF SODIUM AND ZINC INSERTION INTO ALPHA-UO3-Y AND ALPHA-U3O8

被引：3

作者：

DUEBER, RE ^{[1
]}

PATAT, S ^{[1
]}

DICKENS, PG ^{[1
]}

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,S PK RD,OXFORD OX1 3QR,ENGLAND

来源：

SOLID STATE IONICS | 1995年 / 80卷 / 3-4期

关键词：

INTERCALATION; THERMODYNAMICS; URANIUM OXIDE;

D O I：

10.1016/0167-2738(95)00119-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New sodium and zinc insertion compounds of the uranium oxides UO2.95(alpha-UO3) and UO2.67(alpha-U3O8), were synthesized at ambient temperature. Enthalpies of formation were measured calorimetrically and corresponding free energies of formation were determined electrochemically. Electronic changes on insertion were monitored by measurements of magnetic susceptibilities.

引用

页码：231 / 238

页数：8

共 19 条

[1] COMPUTER-SIMULATION STUDY OF ALKALI-METAL INSERTION INTO ALPHA-U3O8 [J].

BALL, RGJ ;

DICKENS, PG .

JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (03) :415-421

[2]

Basu S., 1979, Fast Ion Transport in Solids. Electrodes and Electrolytes, P149

[3]

CHASE MW, 1985, J CHEM REF DATA S, V1

[4] INSERTION COMPOUNDS OF TRANSITION-METAL AND URANIUM-OXIDES [J].

CHIPPINDALE, AM ;

DICKENS, PG ;

POWELL, AV .

PROGRESS IN SOLID STATE CHEMISTRY, 1991, 21 (03) :133-198

[5] STANDARD ENTHALPIES OF FORMATION OF URANIUM-COMPOUNDS .7. UF3 AND UF4 (BY SOLUTION CALORIMETRY) [J].

CORDFUNKE, EHP ;

OUWELTJES, W .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1981, 13 (02) :193-197

[6] INTERCALATION COMPOUNDS OF SOME MIXED OXIDES OF URANIUM [J].

DICKENS, PG ;

STUTTARD, GP ;

DUEBER, RE ;

WOODALL, MJ ;

PATAT, S .

SOLID STATE IONICS, 1993, 63-5 :417-423

[7] HYDROGEN INSERTION COMPOUNDS OF UO3 [J].

DICKENS, PG ;

HAWKE, SV ;

WELLER, MT .

MATERIALS RESEARCH BULLETIN, 1984, 19 (05) :543-547

[8] LITHIUM INSERTION INTO ALPHA-UO3 AND U3O8 [J].

DICKENS, PG ;

LAWRENCE, SD ;

WELLER, MT .

MATERIALS RESEARCH BULLETIN, 1985, 20 (06) :635-641

[9] STRUCTURE OF THE INSERTION COMPOUND LI0.88U3O8 BY POWDER NEUTRON-DIFFRACTION [J].

DICKENS, PG ;

POWELL, AV .

JOURNAL OF SOLID STATE CHEMISTRY, 1991, 92 (01) :159-169

[10] INSERTION COMPOUNDS OF URANIUM-OXIDES [J].

DICKENS, PG ;

LAWRENCE, SD ;

PENNY, DJ ;

POWELL, AV .

SOLID STATE IONICS, 1989, 32-3 :77-83

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