STRUCTURE AND PHYSICAL-PROPERTIES OF LITHIUM IRON-OXIDE, LIFEO2, SYNTHESIZED BY IONIC EXCHANGE-REACTION

被引：117

作者：

SHIRANE, T

KANNO, R

KAWAMOTO, Y

TAKEDA, Y

TAKANO, M

KAMIYAMA, T

IZUMI, F

机构：

[1] KOBE UNIV,FAC SCI,DEPT CHEM,NADA KU,KOBE,HYOGO 657,JAPAN

[2] MIE UNIV,FAC ENGN,DEPT CHEM,TSU,MIE 514,JAPAN

[3] KYOTO UNIV,INST CHEM RES,UJI,KYOTO 611,JAPAN

[4] UNIV TSUKUBA,INST MAT SCI,TSUKUBA,IBARAKI 305,JAPAN

[5] NATL INST RES INORGAN MAT,TSUKUBA,IBARAKI 305,JAPAN

来源：

SOLID STATE IONICS | 1995年 / 79卷

关键词：

LITHIUM IRON OXIDE; LAYERED ROCK-SALT; LITHIUM CELL; NEUTRON DIFFRACTION;

D O I：

10.1016/0167-2738(95)00066-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Layered LiFeO2 was synthesized by ionic exchange reactions in molten salts from alpha-NaFeO2; its structure was determined by X-ray and neutron diffraction measurements and the magnetic properties were characterized by magnetization measurements and Mossbauer spectroscopy. The reaction conditions were clarified using various molten salts containing lithium, and a ''layered'' sample was obtained by a reaction in LiCl/KCl molten salt at 400 degrees C for 0.5 h; a slightly higher reaction temperature of 500 degrees C gave an orthorhombic LiFeO2. Neutron diffraction data of the ''layered'' LiFeO2 was fitted by a two-phase model with the alpha-NaFeO2 type and a spinel-related type. The Mossbauer spectroscopy indicated two different iron sites, being consistent with the two-phase model.

引用

页码：227 / 233

页数：7

共 22 条

[1] STRUCTURAL STUDIES OF LI0.7VO2 IN THE TEMPERATURE-RANGE 20-300-DEGREES-C
CARDOSO, LP
COX, DE
HEWSTON, TA
CHAMBERLAND, BL
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1988, 72 (02) : 234 - 243
[2] THE CRYSTAL-STRUCTURES OF THE LITHIUM-INSERTED METAL-OXIDES LI0.5TIO2 ANATASE, LITI2O4 SPINEL, AND LI2TI2O4
CAVA, RJ
MURPHY, DW
ZAHURAK, S
SANTORO, A
ROTH, RS
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1984, 53 (01) : 64 - 75
[3] HIGH-PRESSURE-HIGH-TEMPERATURE SYNTHESES .3. DIRECT SYNTHESES OF NEW HIGH-PRESSURE FORMS OF LIALO2 AND LIGAO2 AND POLYMORPHISM IN LIMO2 COMPOUNDS (M=B,AL,GA)
CHANG, CH
MARGRAVE, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (08) : 2020 - &
[4] STRUCTURE AND ELECTROCHEMISTRY OF LI1+/-YNIO2 AND A NEW LI2NIO2 PHASE WITH THE NI(OH)2 STRUCTURE
DAHN, JR
VONSACKEN, U
MICHAL, CA
[J]. SOLID STATE IONICS, 1990, 44 (1-2) : 87 - 97
[5] INSERTION EXTRACTION REACTIONS OF LITHIUM WITH LIV2O4
DEPICCIOTTO, LA
THACKERAY, MM
[J]. MATERIALS RESEARCH BULLETIN, 1985, 20 (12) : 1409 - 1420
[6] SYNTHESIS OF LIMNO2 AND LIFEO2 IN MOLTEN LI HALIDES
FUCHS, B
KEMMLERSACK, S
[J]. SOLID STATE IONICS, 1994, 68 (3-4) : 279 - 285
[7] PRESENTATION OF NEW-TYPE NACL SUPERSTRUCTURE - STRUCTURE OF TNAO2 COMPOUNDS (T = DY, HO, Y, ER)
GONDRAND, M
BRUNEL, M
DEBERGEV.F
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (MAR15): : 722 - &
[8] A REINVESTIGATION OF THE STRUCTURES OF LITHIUM-COBALT-OXIDES WITH NEUTRON-DIFFRACTION DATA
GUMMOW, RJ
LILES, DC
THACKERAY, MM
DAVID, WIF
[J]. MATERIALS RESEARCH BULLETIN, 1993, 28 (11) : 1177 - 1184
[9] MAGNETIC PROPERTIES OF ALPHA-NAFEO2
ICHIDA, T
SHINJO, T
BANDO, Y
TAKADA, T
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1970, 29 (03) : 795 - &
[10] Izumi F., 1993, RIETVELD METHOD, pch13

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