CARBON-SULFUR BOND-CLEAVAGE BY COBALT - REACTION OF CP-ASTERISK-CO(C2H4)2 WITH DIBENZOTHIOPHENE

被引：49
作者：
JONES, WD
CHIN, RM
机构：
[1] Department of Chemistry, University of Rochester, Rochester
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 472卷 / 1-2期
基金：
美国国家科学基金会;
关键词：
COBALT; CYCLOPENTADIENYL; THIOLATE; THIOPHENE; CRYSTAL STRUCTURE; DESULFURIZATION;
D O I：
10.1016/0022-328X(94)80217-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The thermal reaction of Cp*Co(C2H4)2 with thiophene yields the C-S insertion product [CP*Co]2(mu-eta2,eta3-C4H4S). Reaction with dibenzothiophene produces the analogous dinuclear C-S insertion adduct [CP*Co]2(mu-eta2,eta3-C12H8S) the crystal structure of which was determined. Reaction of the thiophene insertion adduct with H2S gives a new butadienedithiolate compound in which sulfur has inserted into the metal-carbon bond, [CP*Co]2(mu-eta2,eta2-S2C4H4).
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页码：311 / 316
页数：6
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