THE PREPARATION AND CRYSTAL-STRUCTURE OF BIS(CYCLOPENTADIENYL)(2,6-DIPHENYLPHENOXO)-BIS(TETRAHYDROFURAN)NEODYMIUM(III) - AN UNEXPECTED EXAMPLE OF FORMAL 9 COORDINATION

被引：13

作者：

DEACON, GB ^{[1
]}

NICKEL, S ^{[1
]}

TIEKINK, ERT ^{[1
]}

机构：

[1] UNIV ADELAIDE,DEPT PHYS & INORGAN CHEM,ADELAIDE,SA 5001,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 409卷 / 1-2期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/0022-328X(91)86156-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of NdCp3 (Cp = cyclopentadienyl) with an equimolar amount of 2,6-diphenylphenol (HOdpp) in tetrahydrofuran (thf) yields the formally nine-coordinate [NdCp2(Odpp)(thf)2]. The crystal structure shows a distorted trigonal bipyramidal arrangement of oxygen donor atoms and cyclopentadienyl ring centroids, with the thf oxygens in the axial positions and a two-fold axis along the Nd-Odpp bond.

引用

页码：C1 / C4

页数：4

共 19 条

[1] ORGANOLANTHANOIDS .11. THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2 TRIS(ETA-5-CYCLOPENTADIENYL)(PYRIDINE)-LANTHANOID(III) COMPOUNDS [J].

DEACON, GB ;

GATEHOUSE, BM ;

PLATTS, SN ;

WILKINSON, DL .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1987, 40 (05) :907-914

[2] ORGANOAMIDO-LANTHANOIDS AND ARYLOXO-LANTHANOIDS .2. PREPARATION OF TRIS(2,6-DIPHENYLPHENOXO)-LANTHANOID(III) COMPLEXES AND THE X-RAY STRUCTURES OF LOW-COORDINATE [YB(O-2,6-PH2C6H3)3] CONTAINING AN INTRAMOLECULAR CHELATE YB ... PI-ARENE INTERACTION, AND [YB(O-2,6-PH2C6H3)3(THF)2].THF (THF = TETRAHYDROFURAN) [J].

DEACON, GB ;

NICKEL, S ;

MACKINNON, P ;

TIEKINK, ERT .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1990, 43 (07) :1245-1257

[3] ORGANOLANTHANOIDS .5. THE CRYSTAL AND MOLECULAR-STRUCTURE OF DI-ETA-5-CYCLOPENTADIENYL-1,2-DIMETHOXYETHANEYTTERBIUM(II) [J].

DEACON, GB ;

MACKINNON, PI ;

HAMBLEY, TW ;

TAYLOR, JC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 259 (01) :91-97

[4] VARIABLE COORDINATION NUMBERS IN CRYSTALLINE BIS(PENTAMETHYLCYCLOPENTADIENYL)SAMARIUM OXIDE, IODIDE AND ALKOXIDE COMPLEXES [J].

EVANS, WJ ;

DRUMMOND, DK ;

HUGHES, LA ;

ZHANG, HM ;

ATWOOD, JL .

POLYHEDRON, 1988, 7 (18) :1693-1703

[5] ORGANOLANTHANIDE AND ORGANOYTTRIUM ENOLATE CHEMISTRY - SYNTHESIS OF [(C5H4R)2LN(MU-OCH=CH2)]2 COMPLEXES AND THE MOLECULAR-STRUCTURE OF [(CH3C5H4)2Y(MU-OCH=CH2)]2 [J].

EVANS, WJ ;

DOMINGUEZ, R ;

HANUSA, TP .

ORGANOMETALLICS, 1986, 5 (07) :1291-1296

[6] SYNTHESIS AND REACTIVITY OF THE CATIONIC ORGANOSAMARIUM(III) COMPLEX [(C5ME5)2SM(THF)2][BPH4], INCLUDING THE SYNTHESIS AND STRUCTURE OF A METALLOCENE WITH AN ALKOXY-TETHERED C5ME5 RING, (C5ME5)2SM[O(CH2)4C5ME5](THF) [J].

EVANS, WJ ;

ULIBARRI, TA ;

CHAMBERLAIN, LR ;

ZILLER, JW ;

ALVAREZ, D .

ORGANOMETALLICS, 1990, 9 (07) :2124-2130

[7] SYNTHESIS AND STRUCTURE OF AN ORGANOSAMARIUM ARYLOXIDE COMPLEX, (C5ME5)2SM(OC6HME4-2,3,5,6) [J].

EVANS, WJ ;

HANUSA, TP ;

LEVAN, KR .

INORGANICA CHIMICA ACTA-F-BLOCK ELEMENTS ARTICLES AND LETTERS, 1985, 110 (03) :191-195

[8]

Forsberg J. H., 1983, GMELIN HDB INORGA D6, P137

[9]

JOHNSON CK, 1971, ORNL2794 REP

[10] INFRARED SPECTRA OF SOME ADDITION COMPOUNDS OF ALUMINIUM AND GALLIUM TRIHALIDES [J].

LEWIS, J ;

MILLER, JR ;

RICHARDS, RL ;

THOMPSON, A .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (NOV) :5850-&

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