N '-(3,5-Dichloro-2-hydroxybenzylidene)-4-(dimethylamino)benzohydrazide methanol monosolvate

被引:1
作者
Xu, Huanzhi [1 ]
Sun, Jingya [1 ]
机构
[1] Zhejiang Ocean Univ, Coll Marine Sci, Zhoushan 316000, Peoples R China
关键词
D O I
10.1107/S1600536812010148
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C16H15Cl2N3O2 center dot CH3OH, a Schiff base molecule, is prepared by the reaction of 3,5-dichlorosalicyl-aldehyde with 4-dimethylaminobenzohydrazide in methanol. The Schiff base molecule is approximately planar, with a mean deviation from the least-squares plane defined by the non-H atoms of 0.0452 (3) angstrom, and with a dihedral angle between the benzene rings of 4.2 (3)degrees. This planarity is assisted by the formation of an intramolecular O-H center dot center dot center dot N hydrogen bond. In the crystal, adjacent Schiff base molecules are linked by two methanol molecules through N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds, forming dimers.
引用
收藏
页码:O1042 / +
页数:7
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