Bis(mu-diisopropylhydoxylaminato)-kappa O-2:N; kappa O-2:O-bis[(diisopropylhydoxylaminato-kappa O) beryllium]

被引：3

作者：

Berger, Raphael Johann Friedrich ^{[1
]}

Jana, Surajit ^{[2
]}

Monkowius, Uwe ^{[3
]}

Mitzel, Norbert Werner ^{[4
]}

机构：

[1] Paris Lodron Univ Salzburg, Fachbereich Mat Wissench & Phys, A-5020 Salzburg, Austria

[2] Asansol Girls Coll, Dept Chem, Asansol 713304, W Bengal, India

[3] Johannes Kepler Univ Linz, Inst Anorgan Chem, Altenbergerstr 69, A-4040 Linz, Austria

[4] Univ Bielefeld, Lehrstuhl Anorgan Chem & Strukturchem, D-33615 Bielefeld, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

D O I：

10.1107/S1600536812045655

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Be-2(C6H14NO)(4)], was prepared from a solution of BeCl2 in diethyl ether and two equivalents of Olithiated N, N-diisopropylhydoxylamine. The molecular structure is composed of a dinuclear unit forming a central fivemembered planar Be-O-Be-O-N ring (sum of internal angles = 540.0 degrees; r.m.s. deviation from planarity = 0.0087 angstrom). Both Be atoms show the unusual coordination number of three, with one Be atom coordinated by three O atoms and the other by two O atoms and one N atom, both in distorted trigonal-planar environments. The Be-O distances are in the range 1.493 (5)-1.600 (5) angstrom and the Be-N distance is 1.741 (5) angstrom.

引用

页码：M1463 / +

页数：10

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