Bis(mu-diisopropylhydoxylaminato)-kappa O-2:N; kappa O-2:O-bis[(diisopropylhydoxylaminato-kappa O) beryllium]

被引：3
|
作者：
Berger, Raphael Johann Friedrich [1 ]
Jana, Surajit [2 ]
Monkowius, Uwe [3 ]
Mitzel, Norbert Werner [4 ]
机构：
[1] Paris Lodron Univ Salzburg, Fachbereich Mat Wissench & Phys, A-5020 Salzburg, Austria
[2] Asansol Girls Coll, Dept Chem, Asansol 713304, W Bengal, India
[3] Johannes Kepler Univ Linz, Inst Anorgan Chem, Altenbergerstr 69, A-4040 Linz, Austria
[4] Univ Bielefeld, Lehrstuhl Anorgan Chem & Strukturchem, D-33615 Bielefeld, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S1600536812045655
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Be-2(C6H14NO)(4)], was prepared from a solution of BeCl2 in diethyl ether and two equivalents of Olithiated N, N-diisopropylhydoxylamine. The molecular structure is composed of a dinuclear unit forming a central fivemembered planar Be-O-Be-O-N ring (sum of internal angles = 540.0 degrees; r.m.s. deviation from planarity = 0.0087 angstrom). Both Be atoms show the unusual coordination number of three, with one Be atom coordinated by three O atoms and the other by two O atoms and one N atom, both in distorted trigonal-planar environments. The Be-O distances are in the range 1.493 (5)-1.600 (5) angstrom and the Be-N distance is 1.741 (5) angstrom.
引用
收藏
页码：M1463 / +
页数：10
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