ARENERUTHENIUM COMPLEXES WITH S2CPR3 AND TRICHLOROSTANNATE

被引：6

作者：

ALVAREZ, B ^{[1
]}

MIGUEL, D ^{[1
]}

PEREZMARTINEZ, JA ^{[1
]}

RIERA, V ^{[1
]}

机构：

[1] UNIV OVIEDO,DEPT QUIM ORGANOMET,E-33071 OVIEDO,SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 474卷 / 1-2期

关键词：

RUTHENIUM; TIN; ARENE;

D O I：

10.1016/0022-328X(94)84058-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes [((eta6-arene) RuCl2)2] (arene = benzene, p-cymene or hexamethylbenzene), react with trialkylphosphine-carbon disulfide fide adducts, S2CPR3 (R = cyclohexyl, Cy; or isopropyl, (i)Pr), in refluxing ethanol in the presence of KPF6 to afford cationic complexes [(eta6-arene)Ru(S2CPR3)Cl]PF6, which have been characterized by analytical and spectroscopic methods. These complexes react with SnCl2 in CH2Cl2/THF to afford trichlorostannato-derivatives [(eta6-arene)Ru(S2CPR3)(SnCl3)]PF6 through insertion of SnCl2 into the Ru-Cl bond.

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收藏

页码：143 / 147

页数：5

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