ONE-STEP TRANSFORMATION OF COORDINATED CO INTO CH2 ON DIRUTHENIUM COMPLEXES BY THE ACTION OF HYDROSILANES - A MODEL SYSTEM FOR THE FISCHER-TROPSCH MECHANISM

被引：22

作者：

AKITA, M

OKU, T

MOROOKA, Y

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 14期

关键词：

D O I：

10.1039/c39920001031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By treatment with dihydrosilanes at 150-degrees-C a diruthenium carbonyl complex Ru2(C5H5)2(mu-CO)2(CO)2 is sequentially transformed into a mu-methylene complex Ru2(C5H5)2(mu-CH2)(mu-CO)(CO)2 and a di(mu-methylene) complex Ru2(C5H5)2-(mu-CH2)2(CO)2.

引用

页码：1031 / 1032

页数：2

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