DIAQUADIPHENYLBIS(P-TOLUENESULFONATO)LEAD WATER (1/1)

被引:5
|
作者
HUBER, F
REMER, J
SCHURMANN, M
机构
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1994年 / 50卷
关键词
D O I
10.1107/S0108270194007808
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The polyhedron around the Pb atom in [Pb(C7H7SO3)(2)(C6H5)(2)(H2O)(2)].H2O is a slightly distorted pentagonal bipyramid, with two C(phenyl) atoms in the apical positions and three sulfonate O atoms and two O atoms of the coordinated water molecules forming the pentagonal plane. One sulfonate ligand is monodentate, the second is bidentate and links a neighbouring molecule to form a chain {i.e. catenapoly [diaquadiphenyl(p-toluenesulfonato-O)lead-mu-(p-toluenesulfonato)-O:O']}. The chains are linked by the non-coordinated water molecules to form a two-dimensional network.
引用
收藏
页码:1913 / 1915
页数:3
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