CATALYTIC DECOMPOSITION OF POTASSIUM CHLORATE

被引：9

作者：

CANNON, JC

ZHANG, YC

机构：

[1] Puritan-Bennett Corp., Lenexa, 66215, Kansas

来源：

JOURNAL OF THERMAL ANALYSIS | 1994年 / 41卷 / 05期

关键词：

CATALYTIC ACTIVITY; POTASSIUM CHLORATE; TG-DTA;

D O I：

10.1007/BF02547189

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermal decomposition of potassium chlorate in the presence of various additives is studied using thermogravimetric analysis and differential thermal analysis. Catalytic effects of metal oxides with comparable surface areas are compared, and the catalytic effects of a number of non-oxide additives are also studied. The nonoxide additives show catalytic activities similar to the corresponding metal oxides. Metal cations and their electron configurations determine the catalytic activity of various compounds. Metal cations with partially filled d shells have the highest activity, transition metal cations with completely empty d orbitals are moderated active, and metal cations with completely filled d shells or noble gas configurations have minimum activity.

引用

收藏

页码：981 / 993

页数：13

相关论文

共 14 条

[1]

Feng Z., 1988, HUAXUE TONGBAO, V9, P43

[2] OXYGEN EVOLUTION FROM KCLO3 CATALYZED BY METAL-OXIDES AS AIR BAG INFLATORS [J].

IWAKURA, H ;

KAKUTA, N ;

UENO, A ;

KISHI, K ;

KATO, J .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1991, 30 (04) :778-783

[3]

MORISHIMA S, 1991, NIPPON KAGAKU KAISHI, V9, P1172

[4] THE CATALYTIC EFFECTS OF METAL-OXIDES ON THERMAL-DECOMPOSITION REACTIONS .3. THE INFLUENCE OF STRUCTURAL AND ELECTRONIC DEFECTS IN IRON-OXIDES ON THEIR CATALYTIC EFFECTIVENESS WITH RESPECT TO THE THERMAL-DECOMPOSITION OF POTASSIUM CHLORATE [J].

RUDLOFF, WK ;

FREEMAN, ES .

JOURNAL OF THERMAL ANALYSIS, 1980, 18 (02) :359-369

[5] CATALYTIC EFFECT OF METAL OXIDES ON THERMAL DECOMPOSITION REACTIONS .2. CATALYTIC EFFECT OF METAL OXIDES ON THERMAL DECOMPOSITION OF POTASSIUM CHLORATE AND POTASSIUM PERCHLORATE AS DETECTED BY THERMAL ANALYSIS METHODS [J].

RUDLOFF, WK ;

FREEMAN, ES .

JOURNAL OF PHYSICAL CHEMISTRY, 1970, 74 (18) :3317-&

[6] THE EFFECT OF DEFECT STRUCTURE DUE TO DOPING AND IRRADIATION ON THE THERMAL-DECOMPOSITION OF POTASSIUM CHLORATE [J].

RUDLOFF, WK ;

FREEMAN, ES .

JOURNAL OF THERMAL ANALYSIS, 1980, 18 (03) :411-425

[7] CATALYTIC EFFECT OF METAL OXIDES ON THERMAL-DECOMPOSITION REACTIONS .I. MECHANISM OF MOLTEN-PHASE THERMAL DECOMPOSITION OF POTASSIUM CHLORATE AND OF POTASSIUM CHLORATE IN MIXTURES WITH POTASSIUM CHLORIDE AND POTASSIUM PERCHLORATE [J].

RUDLOFF, WK ;

FREEMAN, ES .

JOURNAL OF PHYSICAL CHEMISTRY, 1969, 73 (05) :1209-&

[8] EFFECT OF OXIDE ADDITIVES ON THE THERMAL-DECOMPOSITION OF KCLO4 [J].

SAID, AA ;

HASSAN, EA ;

ELSALAAM, KMA .

SURFACE TECHNOLOGY, 1983, 20 (02) :131-137

[9] EFFECT OF METAL-OXIDE ADDITIVES ON THERMAL-DECOMPOSITION OF PERCHLORATES, OXALATES AND HYDROXIDES [J].

SHIMOKAWABE, M ;

FURUICHI, R ;

ISHII, T .

THERMOCHIMICA ACTA, 1977, 20 (03) :347-361

[10] CATALYSIS OF SOLID PHASE REACTIONS - EFFECT OF DOPING OF CUPRIC OXIDE CATALYST ON THE THERMAL DECOMPOSITION AND EXPLOSION OF AMMONIUM PERCHLORATE [J].

SOLYMOSI, F ;

KRIX, E .

JOURNAL OF CATALYSIS, 1962, 1 (05) :468-480