ORGANOMETALLIC MACROCYCLE CHEMISTRY .1. THE REACTIONS OF [RUCL2(PPH3)3] WITH 1,4,7-TRITHIACYCLONONANE AND 1,4,8,11-TETRATHIACYCLOTETRADECANE

被引：22

作者：

HILL, AF

ALCOCK, NW

CANNADINE, JC

CLARK, GR

机构：

[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

[2] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 426卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)83054-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [RuCl2(PPh3)3] with the thiacrown ethers 1,4,7-trithiacyclononane (9-S3) and 1,4,8,11-tetrathiacyclotetradecane (14-S4) provide the crystallographically characterised complexes [RuCl2(PPh3)(9-S3)] and cis-[RuCl(PPh3)(14-S4)]+. The thiocarbonyl containing salts [RuCl(CS) (PPh3)(9-S3)]ClO4 and [RuH(CS)(PPh3)(9-S3)]ClO4 are obtained by treatment of the complexes [RuCl2(OH2)(CS)(PPh3)2] and [RuClH(CS)(PPh3)3] with 9-S3.

引用

页码：C40 / C43

页数：4

共 6 条

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