REACTION OF 1,2-DITHIOLANE WITH ALPHA-LITHIATED THIOPHENES - SELECTIVE SYNTHESES OF MONO-S-THIENYL-1,3-PROPANEDITHIOLS

被引：6

作者：

TAZAKI, M

TANABE, H

HIEDA, T

NAGAHAMA, S

INOUE, K

TAKAGI, M

机构：

[1] SAGA UNIV,DEPT IND CHEM,SAGA 840,JAPAN

[2] KYUSHU UNIV,FAC ENGN,DEPT CHEM SCI & TECHNOL,HIGASHI KU,FUKUOKA 812,JAPAN

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 88卷 / 1-4期

关键词：

CYCLIC DISULFIDES; 4,4-DISUBSTITUTED 1,2-DITHIOLANE; NUCLEOPHILIC S-S BOND CLEAVAGE; LITHIATED THIOPHENES; MONO-S-THIENYL-1,3-PROPANEDITHIOLS; S3 LIGANDS FOR TRANSITION METALS;

D O I：

10.1080/10426509408036921

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Lithiated thiophenes 3 cleaved S-S bond of 4,4-disubstituted 1,2-dithiolane 1 and naphthalene-1,8-disulfide 5 to give the ring opened products 2 and 6, respectively, in excellent yields.

引用

页码：189 / 193

页数：5

共 15 条

[1]

BABA Y, 1990, PROCESS METALLURGY A, V7, P351

[2]

BERGSON G, 1964, ARK KEMI, V22, P475

[3] ORGANIC SULFUR CHEMISTRY .10. SELECTIVE DESULFURIZATION OF DISULFIDES - SCOPE AND MECHANISM [J].