A MONTE-CARLO STUDY OF THE LIQUID-VAPOR COEXISTENCE OF CHARGED HARD-SPHERES

被引：99
|
作者：
CAILLOL, JM
机构：
[1] Laboratoire de Physique Théorique et Hautes Energies, Bâtiment 211, Université de Paris-Sud
来源：
JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 03期
关键词：
D O I：
10.1063/1.466513
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We determine the liquid-vapor coexistence curve of the restricted primitive model of electrolytes by means of Monte Carlo simulations in the Gibbs ensemble. Our results confirm earlier findings of Panagiotopoulos [Fluid Phase Equilibria 76, 97 (1992)]. A study of the electrical properties of the two coexisting phases reveals that the second Stillinger-Lovett condition is verified in the liquid but not in the vapor. This means that the latter could be dielectric.
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页码：2161 / 2169
页数：9
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