A MONTE-CARLO STUDY OF THE LIQUID-VAPOR COEXISTENCE OF CHARGED HARD-SPHERES

被引：99

作者：

CAILLOL, JM

机构：

[1] Laboratoire de Physique Théorique et Hautes Energies, Bâtiment 211, Université de Paris-Sud

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 03期

关键词：

D O I：

10.1063/1.466513

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We determine the liquid-vapor coexistence curve of the restricted primitive model of electrolytes by means of Monte Carlo simulations in the Gibbs ensemble. Our results confirm earlier findings of Panagiotopoulos [Fluid Phase Equilibria 76, 97 (1992)]. A study of the electrical properties of the two coexisting phases reveals that the second Stillinger-Lovett condition is verified in the liquid but not in the vapor. This means that the latter could be dielectric.

引用

页码：2161 / 2169

页数：9

共 38 条

[1] INABILITY OF THE HYPERNETTED-CHAIN INTEGRAL-EQUATION TO EXHIBIT A SPINODAL LINE [J].