THEORY OF MOSSBAUER LINE BROADENING DUE TO DIFFUSION OF MOSSBAUER ATOMS VIA VACANCIES

We have calculated analytically the effect of diffusion on the Mössbauer line, especially considering the correlation effects due to diffusion via vacancies. Starting from a hierarchy of rate equations for single-particle densities, pair correlation functions, and higher-order correlation functions we have deduced for small vacancy concentrations an effective equation for the motion of Mössbauer atoms which is similar to the well-known encounter model". The transport of Mössbauer atoms is described by an effective jump-frequency matrix which incorporates the temporal and spatial correlations of the atomic jumps induced by a single vacancy. We calculate the effective jump-frequency matrix analytically by an interation with respect to the number of atomic jumps during an encounter. It turns out that the correlation of the atomic jumps diminishes the diffusion broadening of the Mössbauer line. This eliminates some of the discrepancies between Mössbauer studies and radio-tracer experiments. © 1979 The American Physical Society."