LOW-FREQUENCY DISPERSION OF THE PERMITIVITY OF CONCENTRATED SUSPENSIONS OF IONITE PARTICLES

被引:0
作者
BORKOVSKAYA, YB
SHILOV, VN
机构
来源
COLLOID JOURNAL OF THE RUSSIAN ACADEMY OF SCIENCES | 1992年 / 54卷 / 02期
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Calculations are performed to determine the low-frequency dispersion of the permittivity of monodisperse suspensions of spherical particles with a high volumetric or surface value of unipolar conductivity. The use of a cellular model makes it possible to go beyond the framework of a linear approximation of the volume fraction of particles and analyze the effect of this quantity on the low-frequency limit of permittivity, the critical frequency of the dispersion, and the form of the dispersion curves. The results that are obtained explain the observed features of the low-frequency permittivity of concentrated suspensions and makes it possible to determine the parameters of the internal structure of ion-exchange materials by means of the gel-intergel model from measurements of low-frequency dielectric dispersion.
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页码:173 / 180
页数:8
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