ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED ALKENES USING THE NEW C2-SYMMETRICAL 1,1'-BINAPHTHYL-2,2'-DIMETHYLENE-BRIDGED ANSA-BIS(1-INDENYL)TITANIUM DICHLORIDE CATALYST

被引：46

作者：

COLLETTI, SL ^{[1
]}

HALTERMAN, RL ^{[1
]}

机构：

[1] UNIV OKLAHOMA,DEPT CHEM,620 PARRINGTON OVAL,NORMAN,OK 73019

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 08期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)91845-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The asymmetric catalytic epoxidation of various unfunctionalized alkyl and aryl alkenes has been accomplished using the new C2-symmetrical 1,1'-binaphthyl-2,2'-dimethylene-bridged ansa-Bis(1-indenyl)titanium dichloride complex. Enantiomeric excesses of 22% and activities up to 61 turnovers were observed using the (R)(-)-BpDM-(1-ind)2TiCl2 catalyst.

引用

页码：1005 / 1008

页数：4

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