N-OXIDE PROMOTED PAUSON-KHAND CYCLIZATIONS AT ROOM-TEMPERATURE

被引:346
作者
SHAMBAYATI, S
CROWE, WE
SCHREIBER, SL
机构
[1] Department of Chemistry, Harvard University Cambridge
关键词
D O I
10.1016/S0040-4039(00)98052-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Tertiary amine oxides have been utilized to effect cobalt-mediated intramolecular cyclizations of enynes (Pauson-Khand reactions) at room temperature. The stereoselectivity, range and limitations of this method are examined. © 1990.
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页码:5289 / 5292
页数:4
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