THE EMULSION POLYMERIZATION OF METHYL-METHACRYLATE INITIATED BY CE(IV)/DODECYL POLY(ETHYLENE OXIDE) REDOX SYSTEM

被引：5
作者：
COUTINHO, FMB
FURTADO, CRG
机构：
[1] Instituto de Macromoléculas, Universidade Federal do Rio de Janeiro, Rio de Janeiro, 21945 RJ
来源：
EUROPEAN POLYMER JOURNAL | 1992年 / 28卷 / 09期
关键词：
D O I：
10.1016/0014-3057(92)90063-8
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The acidic aqueous emulsion polymerization of methyl methacrylate, initiated by ceric ammonium nitrate-dodecyl poly(ethylene oxide) redox system at 30-degrees, was studied. The polymerization was characterized by a pronounced gel effect and showed deviations from the Smith-Ewart theory established for styrene because of the higher polarity of methyl methacrylate.
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页码：1111 / 1114
页数：4
相关论文
共 27 条
[1]   POLYMERIZATION OF METHYL METHACRYLATE IN AQUEOUS EMULSIONS [J].
BAXENDALE, JH ;
EVANS, MG ;
KILHAM, JK .
JOURNAL OF POLYMER SCIENCE, 1946, 1 (06) :466-474
[2]   RELATION BETWEEN MOLECULAR WEIGHT AND INTRINSIC VISCOSITY FOR POLYMETHYL METHACRYLATE [J].
BAXENDALE, JH ;
BYWATER, S ;
EVANS, MG .
JOURNAL OF POLYMER SCIENCE, 1946, 1 (04) :237-244
[3]  
BLACKLEY DC, 1979, EMULSION POLYM
[4]  
BRANDRUP J, 1989, POLYM HDB
[5]  
Duck E. W., 1966, ENCY POLYM SCI TECHN, V5, P801
[6]  
ELISEEVA VI, 1981, EMULSION POLYM ITS A
[7]   CELLOBIOSE CE(IV) AS A REDOX INITIATING SYSTEM FOR AQUEOUS POLYMERIZATION OF METHYL-METHACRYLATE [J].
FERNANDEZ, MD ;
GUZMAN, GM .
EUROPEAN POLYMER JOURNAL, 1990, 26 (03) :301-307
[8]   AQUEOUS POLYMERIZATION OF METHYL-METHACRYLATE INITIATED BY CE(IV)-ALCOHOL REDOX SYSTEMS - EFFECT OF ACID CONCENTRATION AND ADDITIVES [J].
FERNANDEZ, MD ;
GUZMAN, GM .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (07) :2427-2433
[9]   AQUEOUS POLYMERIZATION OF METHYL-METHACRYLATE INITIATED BY CE(IV)-DISACCHARIDE REDOX SYSTEMS - EFFECTS OF ACID CONCENTRATION AND ADDITIVES [J].
FERNANDEZ, MD ;
GUZMAN, GM .
EUROPEAN POLYMER JOURNAL, 1989, 25 (11) :1165-1168
[10]  
FIESER LF, 1967, REAGENTS ORGANIC SYN, P393
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