Bis[[aqua(1H-imidazo[4,5-f][1,10]-phenanthroline-kappa N-2(6),N-7)cadmium]-bis(mu-pyridine-2,3-dicarboxylato)-kappa N-3,O-2:O-3;kappa O-3(3):N,O-2]

被引:0
作者
Chen, Li-Juan [1 ]
Yang, Ming-Xing [1 ]
Huang, Hua [1 ]
Chen, Xiao-Hua [1 ]
Lin, Shen [1 ]
机构
[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
data-to-parameter ratio = 10.8; mean σ(C-C) = 0.006 Å; R factor = 0.032; single-crystal X-ray study; T = 293 K; wR factor = 0.084;
D O I
10.1107/S160053681200579X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cd 2(C 7H 3NO 4) 2(C 13H 8N 4) 2(H 2O) 2], the Cd II ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxylate (pdc) ligand, one O atom from another pdc ligand and one water molecule in a distorted octahedral geometry. Two Cd II ions are bridged by a pair of pdc ligands, forming a centrosymmetric dinuclear structure. Neighboring dinuclear units are linked by the coordinated water molecules through O - H⋯N and O - H⋯O hydrogen bonds, forming a layer parallel to (011). The layers are further linked into a three-dimensional network through N - H⋯O hydrogen bonds. π-π inter-actions between the IP ligands further stabilize the supra-molecular structure [centroid-centroid distances = 3.579 (3), 3.686 (3), 3.710 (3), 3.766 (3) and 3.841 (3) Å].
引用
收藏
页码:M301 / U754
页数:8
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