OXIDATION REACTIONS WITH HOF AND ADDUCTS OF HOF AND HF WITH ACETONITRILE

被引：24

作者：

DUNKELBERG, O

HAAS, A

KLAPDOR, MF

MOOTZ, D

POLL, W

APPELMAN, EH

机构：

[1] RUHRUNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 2,D-44780 BOCHUM,GERMANY

[2] UNIV DUSSELDORF,INST ANORGAN CHEM & STRUKTURCHEM,D-40225 DUSSELDORF,GERMANY

[3] ARGONNE NATL LAB,DIV CHEM,ARGONNE,IL 60439

来源：

CHEMISCHE BERICHTE | 1994年 / 127卷 / 10期

关键词：

OXIDATION BY HOF; HYPOFLUOROUS ACID; ADDITION COMPOUNDS OF HOF AND HF WITH ACETONITRILE;

D O I：

10.1002/cber.19941271009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In acetonitrile solution HOF oxides CF3SSCF3 via CF3S(O)(n)SCF3 (n = 1, 2) to yield [CF3S(O)2]2O. Analogously, CF3Se(O)OH and CF3SeX (X = Cl, Br) are oxidized via CF3Se(VI) intermediates to provide finally [CF3Se(O)2]2O. With CH3CN at low temperatures HOF and HF form 1:1 adducts, whose structures have been elucidated by low-temperature X-ray structure analysis. Additional proof for the formation of CH3CN . HF in the liquid phase is provided.

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页码：1871 / 1875

页数：5

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