POLYARYLENES AND POLY(ARYLENEVINYLENE)S .12. SYNTHESIS AND CHEMICAL MODIFICATION OF 2 NOVEL POLY(NAPHTHYLENE)S CARRYING SOLUBILIZING PENDANT GROUPS

被引:20
作者
ANTON, U [1 ]
MULLEN, K [1 ]
机构
[1] MAX PLANCK INST POLYMER RES,ACKERMANNWEG 10,W-6500 MAINZ,GERMANY
关键词
D O I
10.1021/ma00058a008
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Two novel alkyl-substituted poly(naphthylene)s were synthesized by a transition-metal-catalyzed coupling of aryl bromides and aromatic boronic acids. Their solubility and substitution pattern make the title structures 3 and 6 suitable for polymer-analogous reactions. Anionic and cationic cyclizations lead to polymers containing two-dimensionally fused substructures (rylene units) of perylene, terrylene, and quaterrylene. Depending on the type of substitution, rylene incorporation ranging from 39 to 78 wt % is achieved. The cyclized materials are promising candidates for charge storage.
引用
收藏
页码:1248 / 1253
页数:6
相关论文
共 25 条
[1]   ELECTRICAL CONDUCTIVITY OF THE PERYLENE-BROMINE COMPLEX [J].
AKAMATU, H ;
INOKUCHI, H ;
MATSUNAGA, Y .
NATURE, 1954, 173 (4395) :168-169
[2]   SYNTHESIS OF N-ALKYL-SUBSTITUTED PERYLENES AND TERRYLENES VIA ALKALI-METAL INDUCED CYCLIZATION OF OLIGONAPHTHYLENES [J].
ANTON, U ;
GOLTNER, C ;
MULLEN, K .
CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (10) :2325-2330
[3]  
BAYER, Patent No. 281513
[4]   POLYPYRROLE AS AN ELECTRODE MATERIAL FOR SECONDARY LITHIUM CELLS [J].
BITTIHN, R ;
ELY, G ;
WOEFFLER, F .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1987, 8 :51-59
[5]   DAS KONDENSATIONSPRINZIP, EIN EINFACHES NEUES PRINZIP IM AUFBAU DER AROMATISCHEN KOHLENWASSERSTOFFE (AROMATISCHE KOHLENWASSERSTOFFE) .42. [J].
CLAR, E .
CHEMISCHE BERICHTE-RECUEIL, 1948, 81 (01) :52-63
[6]  
FAHNENSTICH U, 1989, MAKROMOL CHEM-RAPID, V10, P563
[7]   PERYLENE, A BY-PRODUCT FROM SOME 1-NAPHTHYL-METALLIC COMPOUNDS [J].
GILMAN, H ;
BRANNEN, CG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (02) :657-659
[8]  
HOECHST, Patent No. 1769000
[9]  
HOECHST, Patent No. 176901
[10]  
HORNER L, 1949, ANGEW CHEM, V71, P349