INFRA-RED SPECTRA OF MERCURIC HALIDE ADDUCTS OF SOME CYCLIC THIO-ETHERS

被引：11
作者：
DALZIEL, JAW
HITCH, MJ
ROSS, SD
机构：
[1] Department of Chemistry, Chelsea College of Science and Technology, London, England
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 06期
关键词：
D O I：
10.1016/0584-8539(69)80104-2
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The effect of adduct formation on the ring vibrations of cyclic thio-ethers shows that the mercury-sulphur bond is formed by equatorial donation of the sulphur lone-pair, and varies in strength in the order Cl > Br > I. The mercury is in tetrahedral coordination. © 1969.
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页码：1055 / &
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