GAS-PHASE THERMAL-DECOMPOSITION OF DIETHYLTELLURIDE

被引：0

作者：

DEVYATYKH, GG ^{[1
]}

ZASLONKO, IS ^{[1
]}

SMIRNOV, VN ^{[1
]}

MOISEEV, AN ^{[1
]}

VOTINTSEV, VN ^{[1
]}

TEREZA, AM ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST CHEM HIGH PURITY CPDS,NIZHNII NOVGOROD,RUSSIA

来源：

KINETICS AND CATALYSIS | 1993年 / 34卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Diethyltelluride thermal decomposition was studied behind shock waves over the temperature range 900 - 1100 K at a total density [M] near 5 x 10(-6) mol/CM3 . It was found that the overall decomposition rate is determined by the cleavage of the first Te-C bond. Fitting RRKM calculations to experimental data, we obtained the expressions for the rate constant in low- and high-pressure regimes. A mechanism describing the secondary reactions is proposed.

引用

页码：185 / 189

页数：5

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