GAS-PHASE THERMAL-DECOMPOSITION OF DIETHYLTELLURIDE

被引：0

作者：

DEVYATYKH, GG ^{[1
]}

ZASLONKO, IS ^{[1
]}

SMIRNOV, VN ^{[1
]}

MOISEEV, AN ^{[1
]}

VOTINTSEV, VN ^{[1
]}

TEREZA, AM ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST CHEM HIGH PURITY CPDS,NIZHNII NOVGOROD,RUSSIA

来源：

KINETICS AND CATALYSIS | 1993年 / 34卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Diethyltelluride thermal decomposition was studied behind shock waves over the temperature range 900 - 1100 K at a total density [M] near 5 x 10(-6) mol/CM3 . It was found that the overall decomposition rate is determined by the cleavage of the first Te-C bond. Fitting RRKM calculations to experimental data, we obtained the expressions for the rate constant in low- and high-pressure regimes. A mechanism describing the secondary reactions is proposed.

引用

页码：185 / 189

页数：5

共 17 条

[1]

AKHMADOV VS, 1988, KINET KATAL, V29, P291

[2]

BAEV AK, 1987, 5 VSES SOV PRIM MET, P104

[3]

Burcat A., 1984, COMBUSTION CHEM

[4]

GLUSHKO VP, 1978, TERMODINAMICHESKIE S

[5]

GURYLEV BV, 1988, POLUCHENIE ANAL CHIS, P30

[6] SYNTHESIS OF DIETHYLTELLURIDE AND RAMAN, IR AND PROTON NMR-SPECTRA OF DIETHYLCHALCOGENIDES [J].

HAMADA, K ;

MORISHITA, H .

SPECTROSCOPY LETTERS, 1977, 10 (05) :357-365

[7]

HIRSHFELDER JO, 1963, MOL THEORY GASES LIQ

[8]

HUSSAIN D, 1973, J CHEM SOC F2, V69, P585

[9]

IRVINE SJC, 1984, MATER RES SOC S P, V29, P253

[10]

LUTHER K, 1978, 17TH S INT COMB PITT, P535

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