OPTICAL LIGAND-TO-LIGAND CHARGE-TRANSFER OF ZN(2,2'-BIPYRIDYL) (3,4-TOLUENEDITHIOLATE)

被引：30

作者：

BENEDIX, R ^{[1
]}

HENNIG, H ^{[1
]}

KUNKELY, H ^{[1
]}

VOGLER, A ^{[1
]}

机构：

[1] UNIV REGENSBURG,INST ANORGAN CHEM,W-8400 REGENSBURG,GERMANY

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 175卷 / 05期

关键词：

D O I：

10.1016/0009-2614(90)85568-W

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electronic structure and the optical ligand-to-ligand charge transfer (LLCT) of the pseudotetrahedral complex Zn (2,2'-bipyridyl) (3,4-toluenedithiolate) is interpreted on the basis of EHT calculations. By comparison with square-planar complexes, it is shown that the extent of electron delocalization between donor and acceptor ligand and charge separation by LLCT excitation depends on the mutual orientation of both ligands.

引用

页码：483 / 487

页数：5

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