COORDINATION CHEMISTRY OF PHOSPHORYL COMPOUNDS .I. LANTHANIDE COMPLEXES OF HEXAMETHYL PHOSPHORAMIDE

被引：42

作者：

DONOGHUE, JT

PETERS, DA

机构：

[1] Department of Chemistry, University of Arkansas, Fayetteville

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 02期

关键词：

D O I：

10.1016/0022-1902(69)80490-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of lanthanides of the type LnCl3-3HMPA have been prepared and characterized by means of analytical, conductivity and infrared spectral studies (HMPA = O = P[N(CH3)2]3). It has been found that the lanthanides exhibit the unusual coordination number of six in these compounds. Results also indicate that the ligand is coordinated via its phosphoryl oxygen atom. © 1969.

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页码：467 / &

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