2 NEW [CD(CN)(2)]N FRAMEWORKS WITH LINEAR CHANNELS OF LARGE, ELONGATED HEXAGONAL CROSS-SECTION - STRUCTURES OF CADMIUM CYANIDE-GUEST (GUEST=DMF AND ME(2)SO) CLATHRATES

被引：30

作者：

KIM, J

WHANG, D

KOH, YS

KIM, K

机构：

[1] POHANG UNIV SCI TECHNOL,DEPT CHEM,POHANG 790600,SOUTH KOREA

[2] POHANG UNIV SCI TECHNOL,CTR BIOFUNCT MOLEC,POHANG 790600,SOUTH KOREA

[3] RES INST IND SCI & ENGN,DIV BASIC SCI,POHANG 790600,SOUTH KOREA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 05期

关键词：

D O I：

10.1039/c39940000637

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new [Cd(CN)(2)](n) frameworks with linear channels of large, elongated hexagonal cross-section have been discovered in cadmium cyanide-guest (guest = dmf or Me(2)SO) clathrates; the framework in the latter clathrate is the first example of a 3-D net comprising octahedral and tetrahedral cadmium centres in a 2:1 ratio.

引用

收藏

页码：637 / 638

页数：2

相关论文

共 8 条

[1] A HONEYCOMB FORM OF CADMIUM CYANIDE - A NEW TYPE OF 3-D ARRANGEMENT OF INTERCONNECTED RODS GENERATING INFINITE LINEAR CHANNELS OF LARGE HEXAGONAL CROSS-SECTION [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (01) :60-61

[2] THE ARCHETYPE FOR A NEW CLASS OF SIMPLE EXTENDED 3D HONEYCOMB FRAMEWORKS - THE SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF CD(CN)5/3(OH)1/3.1/3(C6H12N4), CD(CN)2.1/3(C6H12N4), AND CD(CN)2.2/3H2O.TBUOH (C6H12N4 = HEXAMETHYLENETETRAMINE) REVEALING 2 TOPOLOGICALLY EQUIVALENT BUT GEOMETRICALLY DIFFERENT FRAMEWORKS [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

LIU, JP ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :3045-3051

[3] REDUCED MOLYBDENUM PHOSPHATES - OCTAHEDRAL TETRAHEDRAL FRAMEWORK SOLIDS WITH TUNNELS, CAGES, AND MICROPORES [J].

HAUSHALTER, RC ;

MUNDI, LA .

CHEMISTRY OF MATERIALS, 1992, 4 (01) :31-48

[4]

Iwamoto T., 1984, INCLUSION COMPOUNDS, V1, P29

[5] GUEST-DEPENDENT [CD(CN)2]N HOST STRUCTURES OF CADMIUM CYANIDE ALCOHOL CLATHRATES - 2 NEW [CD(CN)2]N FRAMEWORKS FORMED WITH PRNOH AND PRIOH GUESTS [J].

KIM, J ;

WHANG, D ;

LEE, JI ;

KIM, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (18) :1400-1402

[6] NOVEL CLATHRATE COMPOUND OF CADMIUM CYANIDE HOST WITH AN ADAMANTANE-LIKE CAVITY - CADMIUM CYANIDE-CARBON TETRACHLORIDE (1/1) [J].

KITAZAWA, T ;

NISHIKIORI, S ;

KURODA, R ;

IWAMOTO, T .

CHEMISTRY LETTERS, 1988, (10) :1729-1732

[7] TETRAHEDRAL GUEST IN A TETRAHEDRAL CAVITY - A NEOPENTANE MOLECULE ENCAGED IN A 3-DIMENSIONAL CADMIUM CYANIDE FRAMEWORK [J].

KITAZAWA, T ;

NISHIKIORI, S ;

YAMAGISHI, A ;

KURODA, R ;

IWAMOTO, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (05) :413-415

[8] CRYSTAL-STRUCTURE OF CD5(CN)10(H2O)4.4C6H11OH STUDIED BY X-RAY-DIFFRACTION AND SOLID-STATE CD-113 NMR - A NEW TYPE OF CRISTOBALITE-LIKE FRAMEWORK HOST WITH A SITE INTERACTING WITH CYCLOHEXANOL BY HYDROGEN-BONDING [J].

NISHIKIORI, S ;

RATCLIFFE, CI ;

RIPMEESTER, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (22) :8590-8595