OXIDATION OF OLEFINS BY SUPPORTED CHROMIUM OXIDE

被引：66
|
作者：
BAKER, LM
CARRICK, WL
机构：
[1] Polymer Research and Development Department, Union Carbide Corporation, Chemicals and Plastics, Bound Brook, New Jersey
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 02期
关键词：
D O I：
10.1021/jo01266a030
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Olefins react with chromium trioxide supported on silica or silica-alumina to give oxidative cleavage of the double bond, with formation of the corresponding aldehydes and ketones as primary oxidation products. The chromium is reduced to the divalent state, apparently in a one-step process. A concerted mechanism is proposed to explain the observed specificity. © 1968, American Chemical Society. All rights reserved.
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页码：616 / &
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