POWDER NEUTRON-DIFFRACTION STUDY OF ZRTIO4, ZR5TI7O24, AND FENB2O6

被引：87

作者：

BORDET, P ^{[1
]}

MCHALE, A ^{[1
]}

SANTORO, A ^{[1
]}

ROTH, RS ^{[1
]}

机构：

[1] NBS, GAITHERSBURG, MD 20899 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1986年 / 64卷 / 01期

关键词：

CRYSTALS - Growing - IRON COMPOUNDS - Phase Transitions - NEUTRONS - Diffraction;

D O I：

10.1016/0022-4596(86)90119-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The zirconium titanates ZrTiO//4 and Zr//5TiO//2//4 and the iron niobate FeNb//2O//6 have been investigated with neutron diffraction powder technique and the Rietveld method. All three compounds crystalize with the symmetry of space group Pbcn and have lattice parameters a equals 4. 8042(2), b equals 5. 4825(3), c equals 5. 0313(2) A for ZrTiO//4; a equals 14. 3574(6), b equals 5. 3247(3), c equals 5. 0200(2) A for Zr//5Ti//7O//2//4; and a equals 14. 2661(2), b equals 5. 7334(1), c equals 5. 0495(1) A for FeNb//2O//6. Pure zirconium titanate, ZrTiO//4, has the alpha -PbO//2-type structure with a random distribution of the two cations.

引用

页码：30 / 46

页数：17

共 17 条

[1] COHERENT NEUTRON-SCATTERING AMPLITUDES [J].