SYNTHESIS OF 6,16,22,32-TETRAHYDROXY[3.3.3.3]METACYCLOPHANE WITH THE AID OF A NEW COPPER CATALYST

被引：2

作者：

BURNS, DH

MILLER, JD

机构：

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(00)77060-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Metacyclophane 2 has been prepared in 4 steps starting from 2-bromoanisole with the aid of a new copper catalyst. The catalyst was prepared by mixing CuBr-SMe(2) with LiSPh and LiBr in THF.

引用

页码：5189 / 5192

页数：4

共 15 条

[1] SYNTHESIS AND CHARACTERIZATION OF [3.3.3.3]METACYCLOPHANE [J].

BURNS, DH ;

MILLER, JD ;

SANTANA, J .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (23) :6526-6528

[2]

CARPITA A, 1982, SYNTHESIS-STUTTGART, P469

[3] COMPLEXATION OF NEUTRAL MOLECULES BY CYCLOPHANE HOSTS [J].

DIEDERICH, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (03) :362-386

[4]

FREIDMAN L, 1974, J AM CHEM SOC, V96, P7101

[5]

Gutsche C. D., 1989, MONOGRAPHS SUPRAMOLE

[6]

HATHAWAY BJ, 1987, COMPREHENSIVE COORDI, V5, P536

[7] THE PREPARATION OF ALPHA,OMEGA-BIS-PARA-ANISYLALKANES [J].

KADKHODAYAN, M ;

SINGLETON, T ;

HELDRICH, FJ .

SYNTHETIC COMMUNICATIONS, 1984, 14 (08) :707-712

[8] MOLECULAR RECOGNITION IN AQUEOUS-MEDIA - NEW BINDING-STUDIES PROVIDE FURTHER INSIGHTS INTO THE CATION-PI INTERACTION AND RELATED PHENOMENA [J].

KEARNEY, PC ;

MIZOUE, LS ;

KUMPF, RA ;

FORMAN, JE ;

MCCURDY, A ;

DOUGHERTY, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) :9907-9919

[9] SYNTHESIS AND PROPERTIES OF TRIMERIC ORTHO-CHELATED (ARENETHIOLATO)COPPER(I) COMPLEXES [J].

KNOTTER, DM ;

VANMAANEN, HL ;

GROVE, DM ;

SPEK, AL ;

VANKOTEN, G .

INORGANIC CHEMISTRY, 1991, 30 (17) :3309-3317

[10]

LIPSHUTZ BH, 1992, ORG REACTIONS, V41, P149

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