Thermodynamics of Alkali Metal Uranoborates

被引:5
|
作者
Karyakin, N. V. [1 ]
Chernorukov, N. G. [1 ]
Knyazev, A. V. [1 ]
Khomyakova, V. O. [1 ]
Smirnova, N. N. [1 ]
机构
[1] Lobachevsky Nizhni Novgorod State Univ, Nizhnii Novgorod, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1007/s11137-005-0061-2
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The standard enthalpies of formation of crystalline A(I)BUO(5) (A(I) = Li, Na, K, Rb, Cs) at 298.15 K were determined by reaction calorimetry. For these compounds, the heat capacities in the range 10-300 K were determined by adiabatic vacuum calorimetry, and the thermodynamic functions were calculated. The standard entropies and Gibbs energies of formation at 298.15 K and the standard thermodynamic functions of solution of these compounds were calculated.
引用
收藏
页码:136 / 149
页数:14
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