CONTROL OF COPOLYMER COMPOSITION DISTRIBUTIONS IN BATCH AND TUBULAR REACTORS

被引：27

作者：

RAY, WH

GALL, CE

机构：

[1] Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada

来源：

MACROMOLECULES | 1969年 / 2卷 / 04期

关键词：

D O I：

10.1021/ma60010a020

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this paper, the problem of maintaining a specified copolymer composition distribution in a batch reactor is considered. The advantages of temperature control, rather than monomer addition are discussed, and the necessary and sufficient conditions for temperature control in the face of monomer depletion are derived. Examples are worked to illustrate the results for a practical range of temperatures. © 1969, American Chemical Society. All rights reserved.

引用

页码：425 / &

共 5 条

[1] COPOLYMERIZATION [J].

MAYO, FR ;

WALLING, C .

CHEMICAL REVIEWS, 1950, 46 (02) :191-287

[2] INTEGRAL AND DIFFERENTIAL BINARY COPOLYMERIZATION EQUATIONS [J].

MEYER, VE ;

LOWRY, GG .

JOURNAL OF POLYMER SCIENCE PART A-GENERAL PAPERS, 1965, 3 (8PA) :2843-&

[3]

ODRISCOLL KF, 1968, MACROMOLECULES, V1, P367

[4]

ODRISCOLL KF, 1969, MAY AI CH E M CLEV

[5] COPOLYMERIZATION - THE COMPOSITION DISTRIBUTION CURVE [J].

SKEIST, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1946, 68 (09) :1781-1784

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