COBALT TETRA(HYDROQUINONE)PORPHYRIN - AN EFFICIENT ELECTRON-TRANSFER REAGENT IN AEROBIC PD-CATALYZED 1,4-DIACETOXYLATION OF 1,3-CYCLOHEXADIENE

被引：53

作者：

GRENNBERG, H ^{[1
]}

FAIZON, S ^{[1
]}

BACKVALL, JE ^{[1
]}

机构：

[1] UNIV UPPSALA,DEPT ORGAN CHEM,BOX 531,S-75121 UPPSALA,SWEDEN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1002/anie.199302631

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient bifunctional catalyst for the title reaction is cobalt tetra(hydroquinone)-porphyrin 1. The oxidized form of 1 (shown right, R = hydroquinone) has one unit for the interaction with molecular O2, and another for the interaction with the Pd catalyst. Thus, electrons can be transferred rapidly from the Pd complex to O2.

引用

页码：263 / 264

页数：2

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