ELECTROOPTIC PROPERTIES OF AN UNUSUAL GUEST-HOST LIQUID-CRYSTAL MIXTURE - A MAUVE ANTHRAQUINONE DYE IN A FERROELECTRIC ORGANOSILOXANE

被引:7
|
作者
OWEN, H
COLES, HJ
NEWTON, J
HODGE, P
机构
[1] UNIV MANCHESTER,DEPT PHYS,LIQUID CRYSTAL GRP,MANCHESTER M13 9PL,LANCS,ENGLAND
[2] UNIV MANCHESTER,DEPT CHEM,POLYMER SYNTH GRP,MANCHESTER M13 9PL,LANCS,ENGLAND
关键词
FERROELECTRIC; GUEST-HOST; ORGANOSILOXANE; ANTHRAQUINONE;
D O I
10.1080/10587259408033772
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
We examine here the electro-optic properties of an unusual guest-host liquid crystal mixture of a high contrast antbraquinone dye and a new ferroelectric organosiloxane liquid crystal. From measurements of the transition temperatures, tilt angles, spontaneous polarisations and rotational viscosities, we show that dye concentrations as high as 4% w/w have negligible effect upon the host properties. Furthermore, we show that the mixture, with a constant tilt angle of 36 degrees across its smectic-C-* phase range from 50 degrees C down to 10 degrees C, high absorbance and good alignment, produces contrast ratios in the V-V scattering mode of 50:1 or higher, with optical response times of 120 mu s or less at 20 degrees C. We argue that the technological implications of mixtures of this type are important, due to their being composed of only two components and having properties surpassing that of commercial optimised mixtures.
引用
收藏
页码:151 / 159
页数:9
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