KINETIC-STUDY OF THE ELECTROPHILIC REACTION OF TRIALKYLTIN CHLORIDES AND IODINE MONOCHLORIDE

被引：0

作者：

VERBIEST, P ^{[1
]}

VERDONCK, L ^{[1
]}

VANDERKELEN, GP ^{[1
]}

机构：

[1] STATE UNIV GHENT,ALGEMENE & ANORGAN CHEM LAB,KRIJGSLAAN 281,B-9000 GHENT,BELGIUM

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1993年 / 25卷 / 02期

关键词：

D O I：

10.1002/kin.550250206

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of the electrophilic substitution of several trialkyltin chlorides by iodine monochloride are presented. Rate constants have been determined at four different temperatures and the activation parameters A, E(a), and DELTAS-degrees= are calculated. A mechanism is proposed involving charge-transfer as the driving force for the substitution.

引用

页码：107 / 112

页数：6

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