UNSYMMETRIC DICOPPER(II) COMPLEXES OF DINUCLEATING LIGANDS BEARING CHEMICALLY DISTINCT COORDINATION ENVIRONMENTS

被引：98
作者：
CRANE, JD
FENTON, DE
LATOUR, JM
SMITH, AJ
机构：
[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND
[2] CEN,DEPT RECH FONDAMENTALE,CHIM LAB,UA 1194,F-38041 GRENOBLE,FRANCE
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 11期
关键词：
D O I：
10.1039/dt9910002979
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Dicopper(II) complexes of unsymmetrical dinucleating Schiff-base ligands bearing chemically distinct co-ordination sites have been prepared and their properties studied. The ligands were derived from the condensation of 4-bromo-2-formyl-6-(4-methylpiperazin-1-ylmethyl)phenol and 4-bromo-2-[(2-diethylaminoethyl)ethylaminomethyl]-6-formylphenol with 2-(aminomethyl)pyridine, 2-(2-aminoethyl)pyridine, and 2-(aminomethyl)-4-nitrophenol.
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页码：2979 / 2987
页数：9
相关论文
共 37 条
[1]   THE CRYSTAL-STRUCTURE OF A MU-PHENOLATO COPPER(II) DINUCLEAR COMPLEX CONTAINING 2 CHEMICALLY DISTINCT METAL COORDINATION ENVIRONMENTS [J].
ADAMS, H ;
CANDELAND, G ;
CRANE, JD ;
FENTON, DE ;
SMITH, AJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (02) :93-95
[2]  
ADAMS H, COMMUNICATION
[3]   CRYSTAL-STRUCTURE OF BIS(PHENYLTRIMETHYLAMMONIUM) DI-MU-BROMO-DIBROMODICUPRATE(I) [J].
ANDERSSON, S ;
JAGNER, S .
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1985, 39 (06) :423-428
[4]  
[Anonymous], 1941, J AM CHEM SOC
[5]   CRYSTAL-STRUCTURE OF BIS(TETRAETHYLAMMONIUM) DI-MU-BROMO-DIBROMODICUPRATE(I), [N(C2H5)4]2[CU2BR4] [J].
ASPLUND, M ;
JAGNER, S .
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1984, 38 (02) :135-139
[6]   CRYSTAL-STRUCTURES OF TETRABUTYLAMMONIUM DICHLOROCUPRATE(I) AND TETRABUTYLAMMONIUM DIBROMOCUPRATE(I), [N(C4H9)4][CUCL2] AND [N(C4H9)4][CUBR2] [J].
ASPLUND, M ;
JAGNER, S ;
NILSSON, M .
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1983, 37 (01) :57-62
[7]   TOWARD COPPER(II) HEMOCYANIN MODELS .2. SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR COPPER(II) COMPLEXES OF A HEPTADENATATE LIGAND [J].
BERENDS, HP ;
STEPHAN, DW .
INORGANIC CHEMISTRY, 1987, 26 (05) :749-754
[8]   COMPARTMENTAL LIGANDS - ROUTES TO HOMO-DINUCLEAR AND HETERO-DINUCLEAR COMPLEXES [J].
CASELLATO, U ;
VIGATO, PA .
CHEMICAL SOCIETY REVIEWS, 1979, 8 (02) :199-220
[9]   SYNTHESIS AND MAGNETIC-PROPERTIES OF BINUCLEAR COPPER(II) COMPLEXES OF 2,6-BIS-(N-2-PYRIDYLFORMIDOLYL)-4-METHYLPHENOL [J].
EDUOK, EE ;
OCONNOR, CJ .
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 88 (02) :229-233
[10]  
EINHORN A, 1905, LIEBIGS ANN CHEM, V343, P223
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