Bis(2,2'-bipyridine-kappa(2) N, N')bis(dicyanamido-kappa N-1) cadmium

被引:2
作者
Mal, Dasarath [1 ]
Sen, Rupam [1 ]
Brandao, Paula [1 ]
Lin, Zhi [1 ]
机构
[1] Univ Aveiro, CICECO, Dept Chem, P-3810193 Aveiro, Portugal
关键词
data-to-parameter ratio = 20.0; mean ̄(C-C) = 0.003 Å; R factor = 0.028; single-crystal X-ray study; T = 150 K; wR factor = 0.069;
D O I
10.1107/S1600536812044108
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cd(C2N3)(2)(C10H8N2)(2)], the Cd-II ion is coordinated in a distorted octahedral environment by four N atoms from two chelating 2,20-bipyridine ligands and two N atoms from two monodentate dicyanamide ligands. The dihedral angle between the mean planes of the two bipyridine ligands is 87.67 (6)degrees.
引用
收藏
页码:M1428 / +
页数:8
相关论文
共 7 条
[1]  
Bruker, 2008, SMART SAINT SADABS
[2]  
Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565, DOI [DOI 10.1107/S0021889897003117, 10.1107/S0021889897003117]
[3]   Syntheses and crystal structures of cadmium(II) coordination polymers with end-to-end dicyanamide bridges [J].
Luo, JH ;
Hong, MC ;
Cao, R ;
Liang, YC ;
Zhao, YJ ;
Wang, RH ;
Weng, JB .
POLYHEDRON, 2002, 21 (08) :893-898
[4]   Encapsulation of [Mn(bpy)3]2+ cations in 2D [Mn(dca)3]- sheet:: Synthesis, X-ray structure and EPR study [J].
Mal, Dasarath ;
Koner, Subratanath ;
Tuchagues, Jean-Pierre ;
Rosair, Georgina M. .
INORGANICA CHIMICA ACTA, 2007, 360 (11) :3575-3580
[5]   Synthesis, X-ray crystal structure and magnetic study of the 1D {[CU2(N,N,N′,N′-tetramethyl-ethylenediamine)2(μ-1,5-dca)2(dca)2]}n complex [J].
Mal, Dasarath ;
Tuchagues, Jean-Pierre ;
Chakraborty, Santu ;
Mukherjee, Alok K. ;
Sen, Rupam ;
Koner, Subratanath .
INORGANICA CHIMICA ACTA, 2006, 359 (13) :4431-4435
[6]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[7]   Bis(2,2 '-bipyridyl-kappa N-2,N ')bis-(dicyanamido-kappa N)manganese(II) [J].
Wang, Haixia ;
Wang, Shaohong ;
Lang, Yuehe .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 :M569-+